Colloidal Silica: Fundamentals And Applications: 131

Description:
In spite of the apparent simplicity of silica's composition and structure, scientists are still investigating fundamental questions regarding the formation, constitution, and behavior of colloidal silica systems. 'Colloidal Silica: Fundamentals and Applications' introduces new information on colloid science related to silica chemistry as well as theoretical and experimental aspects of significant areas of colloidal silica science and technology. This resource is dedicated to helping researchers find new uses of silica and answers to practical problems as its industrial use continues to grow steadily in traditional and novel areas. Written by leading silica scientists around the world, this book reflects developments in the field since silica scientist Ralph K. Iler published his authoritative book on silica chemistry in 1979. It discusses properties and methods of characterization, synthesis, and preparation of silica in terms of industrial applications. Following an analysis of the surface chemistry of various silicas, the book explores methods for measuring particle size and useful characterization techniques for determining structure, stability, and reactivity. The authors then focus on various studies, analytical methods, and current applications involving silica gels and powders, silica coatings, colloidal silica, and sol-gel technology. This book features up-to-date material relating to fields as diverse as catalysis, metallurgy, electronics, glass, ceramics, paper and pulp technology, optics, elastomers, food, health care, and industrial chromatography. It is ideal for scientists interested in silica chemistry and physics as well as those not familiar with the subject.

Table of Contents:
Colloid Science; H.E. Bergna The Language of Colloid Science and Silica Chemistry; H.E. Bergna Colloid Chemistry of Silica: An Overview; H.E. Bergna Silicic Acids and Colloidal Silica; H.E. Bergna PREPARATION OF SOLS; B.A. Keiser Science and Art of the Formation of Uniform Solid Particles; E. Matijevic Silica Nucleation, Polymerization, and Growth Preparation of Monodispersed Sols; A. Yoshida The Formation and Interfacial Structure of Silica Sols; J.D.F. Ramsay, S.W. Swanton, A. Matsumoto, and D.G.C. Goberdhan Synthesis and Characterization of Colloidal Model Particles Made from Organoalkoxysilanes; A. van Blaaderen and A. Vrij Synthesis of Nanometer-Sized Silica by Controlled Hydrolysis in Reverse Micellar Systems; F. J. Arriagada and K. Osseo-Asare Formation of Silica Gels Composed of Micrometer-Sized Particles by the Sol--Gel Method; H. Kozuka and S. Sakka Silica Aquasol Process to Prepare Small Particle Size Colloidal Silica by Electrodialysis; H.E. Bergna Manufacturing and Applications of Water-Borne Colloidal Silica; W.O. Roberts Enterosorbent Silics: Properties and Clinical Application; O.O. Chuiko, O.O. Pentyuk, and V.K. Pogorelyi Industrial Synthetic Silicas in Powder Form; H.K. Ferch High Ratio Silicate Foundry Sand Binders; H.E. Bergna Spray Dried Silica for Chromatography; H.E. Bergna Preparation of Monodisperse Ultrafine Hybrid Silica Particles by Polymer Modification; K. Yoshinaga, J. Shimada, and T. Kobayashi Monodisperse Core-Shell Silica Colloids from Alkoxysilanes; A. van Blaaderen Preparation of Silica Solid Microspheres by Hydrolysis of Tetraethyl Ortho Silicate (TEOS) and Silica Porous Microspheres by Spray Drying Aggregated Colloidal Silica; H.E. Bergna STABILITY OF SOLS; F. Dumont Stability of Aqueous Silica Sols; T.W. Healy Stabilization Against Particle Growth; P.C. Yates SURFACE CHEMISTRY OF SILICA; M.L. Hair The Surface Chemistry of Silica -- The Zhuravlev Model; L.T. Zhuravlev Surface Structure of Amorphous and Crystalline Porous Silicas: Status and Prospects; K.K. Unger Infrared Study of Chemical and H--D Exchange Probes for Silica Surfaces; B.A. Morrow and A.J. McFarlan Infrared Studies of Chemically Modified Silica; B.A. Morrow and D.T. Molapo Fourier Transform Infrared and Raman Spectroscopic Study of Silica Surfaces; B. Humbert, C. Carteret, A. Burneau and J.P. Gallas Adsorption on Silica and Related Materials; L.E. Cascarini de Torre and E.J. Bottani Structure of Disperse Silica Surface and Electrostatic Aspects of Adsorption; A.A. Chuiko, V.V. Lobanov, and A.G. Grebenyuk Variable-Temperature Diffuse Reflectance Fourier Transform Infrared Spectroscopic Studies of Amine Desorption from a Siliceous Surface; D.E. Leyden and K.G. Proctor Surveying the Silica Gel Surface with Excited States; R. Krasnansky and J.K. Thomas Surface Chemistry and Surface Energy of Silicas; A.M. Vidal and E. Papirer Diffuse Reflectance FTIR Spectroscopic Study of Base Desorption from Thermally Treated Silica; K.G. Proctot, S.J. Markway, M. Garcia, C.A. Brown, and C.P. Gonzales Salient Features of Synthesis and Structure of Surface of Functionalized Polysiloxane Xerogels; Yu.L. Zub and A.A. Chuiko Multinuclear NMR Studies of Silica Surfaces; G.E. Maciel and I. Chuang Modified Silicas: Synthesis and Applications; A.A. Chuiko Electric Surface Properties of Silica in Non-aqueous Electrolyte Solutions; A.N. Zhukov Chemical Reactions at Fumed Silica Surfaces; V.M. Gun'ko and A.A. Chuiko Structural and Adsorptive Characteristics of Fumed Silicas in Different Media; V.M. Gun'ko, V.I. Zarko, V.V. Turov, E.F. Voronin, I.F. Mironyuk, A.A. Chuiko Adsorption of Surfactants and Polymers on Silica; P. Somasundaran and L. Zhang PARTICLE SIZE AND CHARACTERIZATION TECHNIQUES; J.L. Bass New Separation Methods for Characterizing the Size of Silica Sols; J. J. Kirkland Characterization of Colloidal and Particulate Silica by Field-Flow Fractionation; J.C. Giddings, S.K. Ratanathanawongs, B.N. Barman, M.H. Moon, G. Liu, B.L. Tjelta, and M.E. Hansen Formation of Uniform Precipitates from Alkoxides; C.F. Zukoski, J.L. Look, and G.H. Bogush SILICA GELS AND POWDERS; W.A. Welsh Synthetic Amorphous Silicas; U. Brinkmann, M. Ettlinger, D. Kerner and R. Schmoll Adsorptive Properties of Porous Silicas; Martyn B. Kenny and K.S.W. Sing Silica Gels from Aqueous Silicate Solutions: Combined 29Si NMR and Small-Angle X-Ray Scattering Spectroscopic Study; P.W.J.G. Wijnen, T.P.M. Beelen, and R.A. van Santen Interpretation of the Differences Between the Pore Size Distributions of Silica Measured by Mercury Intrusion and Nitrogen Adsorption; A.R. Minihan, D.R. Ward, and W. Whitby SOL--GEL TECHNOLOGY; G.W. Scherer Sol--Gel Processing of Silica; C.J. Brinker The Chemistry of Hydrolysis and Condensation of Silica Sol--Gel Precursors; B.K. Coltrain and L.W. Kelts Chemistry and Properties of Porous, Organically Modified Silica; H. Schmidt and H. Bottner Evaporation and Surface Tension Effects in Dip Coating; A.J. Hurd SILICA COATINGS; M.R. Baloga Nanostructuring Metals and Semiconductors with Silica from Monolayers to Crystals; L.M. Liz-Marzan and P. Mulvaney Surface Chemistry of Silica Coatings of Titania; D.N. Furlong Dense Silica Coatings on Micro- and Nanoparticles by Deposition of Monosilicic Acid; H.E. Bergna, L.E. Firment, and D.G. Swartzfager USES OF COLLOIDAL SILICAS; R.E. Patterson and J.S. Falcone Applications of Colloidal Silica: Past, Present, and Future; C.C. Payne The Uses of Soluble Silica; J.S. Falcone, Jr. Attrition Resistant Catalysts, Catalyst Precursors and Catalyst Supports and Process for Preparing Same; H.E. Bergna Some Important, Fairly New Uses of Colloidal Silica/Silica Sol; J.E. Otterstedt and P. Greenwood Silicon--Aluminum Interactions and Biology; J. D. Birchall Silica in Biology; J.S. Falcone Preparation and Uses of Silica Gels and Precipitated Silicas; R.E. Patterson Foundry Mold or Core Compositions and Method; H.E. Bergna Silica Supported Catalysts and Method of Preparation; H.E. Bergna Molded Amorphous Silica Bodies and Molding Powders for Manufacture of Same; H.E. Bergna High Ratio Silicate Foundry Sand Binders; H.E. Bergna NMR OF SILICA EDGE On the Silica Edge: An NMR Point of View; A.P. Legrand, H. Hommel and J.B. d'Espinose de la Caillerie RESEARCH IN RUSSIA; H.E. Bergna Colloid Chemistry of Silica: Research in the Former Soviet Union; L.T. Zhuravlev ANALYTICAL METHODS; H.E. Bergna Integrated Analytical Methods; H.E. Bergna Index